Methyl formate CAS#107-31-3
High-Purity Organic Intermediate – An important raw material for organic synthesis, suitable for a wide range of industrial and chemical applications.
Excellent Solubility – Easily dissolves in water, alcohols, and ethers, providing flexibility for various formulations and processing requirements.
Pleasant Odor Characteristics – Features a mild, pleasant aroma, making it an ideal ingredient for fragrance and flavor-related applications.
Wide Industrial Applications – Commonly used in fragrances, solvents, organic synthesis, bactericides, and insecticides, offering excellent versatility across multiple industries.
Methyl Formate CAS 107-31-3
Methyl formate is a formic acid ester that appears as a colorless, transparent, and volatile liquid at room temperature with a pleasant odor. It is soluble in water, alcohols, and ethers, and can be saponified by water and alkaline solutions. The compound is easily hydrolyzed in the presence of moisture. Its vapor can form explosive mixtures with air, with an explosive concentration range of 6.0%–20.0% (v/v). As an important intermediate in organic synthesis, methyl formate is widely used in the production of fragrances, solvents, organic synthesis chemicals, bactericides, and insecticides.
| Melting point | -100 °C (lit.) |
| Boiling point | 32-34 °C (lit.) |
| density | 0.974 g/mL at 20 °C (lit.) |
| vapor density | 2.1 (vs air) |
| vapor pressure | 32.91 psi ( 55 °C) |
| refractive index | n20/D 1.343(lit.) |
| Fp | −16 °F |
| storage temp. | Store below +30°C. |
| solubility | 300g/l, 25% soluble in water, miscible with alcohol, Propylene glycol, Glycerin and oils. |
| form | Liquid |
| color | Clear colorless |
| Odor | Pleasant; agreeable. |
| PH | 4-5 (200g/l, H2O, 20℃) |
| explosive limit | 5-23%(V) |
| Odor Threshold | 130ppm |
| Odor Type | fruity |
| biological source | synthetic |
| Water Solubility | 300 G/L (20 ºC) |
| Thermal Conductivity | 0.187 W/(m·K) at 25 ℃ |
| λmax | λ: 259 nm Amax: 1.00 |
| λ: 260 nm Amax: 0.70 | |
| λ: 265 nm Amax: 0.20 | |
| λ: 270 nm Amax: 0.04 | |
| λ: 310-400 nm Amax: 0.01 | |
| Merck | 146077 |
| BRN | 1734623 |
| Henry's Law Constant | 0.90 at 5.00 °C, 1.18 at 10.00 °C, 1.51 at 15.00 °C, 1.91 at 20.00 °C, 2.36 at 25.00 °C (column stripping-UV, Kutsuna et al., 2005) |
| Exposure limits | TLV-TWA 100 ppm (~250 mg/m3) (ACGIH, MSHA, and OSHA); TLV-STEL 150 ppm (~375 mg/m3) (ACGIH); IDLH 5000 ppm (NIOSH). |
| Dielectric constant | 8.5(20℃) |
| Stability: | Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point and very wide explosion limits. Incompatible with oxidizing agents. |
| Major Application | cleaning products |
| cosmetics | |
| flavors and fragrances | |
| food and beverages | |
| personal care | |
| InChI | 1S/C2H4O2/c1-4-2-3/h2H,1H3 |
| InChIKey | TZIHFWKZFHZASV-UHFFFAOYSA-N |
| SMILES | [H]C(=O)OC |
| LogP | -0.21 at 25℃ |
| CAS DataBase Reference | 107-31-3(CAS DataBase Reference) |
| NIST Chemistry Reference | Methyl formate(107-31-3) |
| EPA Substance Registry System | Methyl formate (107-31-3) |
Product Application of CAS#107-31-3
Methyl formate is used as a raw material in the production of cellulose acetate and DMF. It also serves as a solvent for the pesticide carbendazim, a curing agent for phenolic resins, and a fumigant for fruits and various tobacco products.




